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I remember music was a big deal to a lot of people with Half Life 2 (me included), so here is the list for Episode 1, in order of appearance.
PS: If you're too lazy to make titles, I included mine.
PPS: Get and use GCFScape before anyone asks where to get these. :hmph: (Path for the music files is "episode 1 shared.gcf" - root - episodic - sound - music)
VLVX_song1
Rollermine/stalker room
Forced Action
VLVX_song2
Combine advisor room (AKA the room with lots of red light in the Citadel)
Combine
VLVX_song19a
When you enter the core
The Core
VLVX_song8
First dark room/after empty turret tunnel/before completely black tunnel
Lowlife
VLVX_song11
Just after you see your first zombine
Zombine
VLVX_song19b
The elevator room
Quiet
VLVX_song12
The elavator room, after all hell breaks loose
Belated Salvation
VLVX_song4
After antlion guard arena/when Alyx mans the "machinegun"